2023 –至今 深圳大学，化学与环境工程学院，副研究员
2020 – 2023 深圳大学，博士后，导师：李霄鹏教授
2018 – 2019 美国南佛罗里达大学，联合培养，导师：李霄鹏教授
2014 – 2020 苏州大学，博士，导师：屠迎锋教授
2010 – 2014 苏州大学，学士
2023 – present Shenzhen University, Associate Research Fellow
2020 – 2023 Shenzhen University, Postdoc (Supervisor: Prof. Xiaopeng Li)
2018 – 2019 University of South Florida, Joint Training Ph.D. Student (Supervisor: Prof. Xiaopeng Li)
2014 – 2020 Soochow University, Ph.D. (Supervisor: Prof. Yingfeng Tu)
2010 – 2014 Soochow University, B.S.
金属-超分子聚合物因集金属中心的光电磁和催化性质、聚合物的机械性能和加工性能以及配位键的刺激响应性于一身而备受关注。此外，配位元素、配体结构、金属离子和相应抗衡离子种类的多样性使金属-超分子聚合物的类型丰富多样，便于按需调控。然而，由于复杂的构筑成分和动态的配位相互作用，导致金属-超分子聚合物的可控制备极具挑战。对此，我们的研究方向围绕以下三个方面展开：
（1）将可控共价聚合和配位驱动自组装相结合实现金属-超分子聚合物的可控制备。
（2）通过增加三联吡啶配体的配位点密度以及形状互补性，提升配位驱动自组装结构的稳定化能，实现金属-超分子聚合物的可控制备。
（3）发展调控配位键键强的新策略，稳定经配位驱动自组装精准构筑的聚集体，实现金属-超分子聚合物的可控制备。
Metallo-supramolecular polymers have attracted extensive attention due to their combination of the optical, electrical, magnetic and catalytic properties of metal centers, the mechanical and processing properties of polymers and the stimulus-responsive properties of coordination bonds. Moreover, the wide range of coordination elements, ligand structures, metal ions and corresponding counterions endows the variability of metallo-supramolecular polymers, which induces them easy to be modified on demand. However, a formidable challenge still remains for the controllable preparation of metallo-supramolecular polymers because of the complex compositions and dynamic coordination bonds. As such, our research mainly focuses on the following aspects.
(1) Combining the controlled covalent polymerization and coordination-driven self-assembly to realize the controllable preparation of metallo-supramolecular polymers.
(2) Controllable preparation of metallo-supramolecular polymers through increasing the density of coordination sites and shape complementarity of terpyridine ligands to enhance the stabilization of coordination-driven self-assembled structures.
(3) Development of new strategies to regulate the strength of coordination bonds and stabilization of the aggregates constructed precisely by coordination-driven self-assembly to realize the controllable preparation of metallo-supramolecular polymers.
1. Li, Z.; Chen, M.; Zhu, Y.-L.; Guo, C.; Wang, H.; Qin, Y.; Fang, F.; Wang, D.; Su, C.; He, C.; Yu, X.;* Lu, Z.-Y.;* Li, X.* Non-equilibrium nanoassemblies constructed by confined coordination on a polymer chain. J. Am. Chem. Soc., 2022, 144, 22651–22661.
2. Li, Z.; Li, Y.; Zhao, Y.; Wang, H.; Zhang, Y.; Song, B.; Li, X.; Lu, S.; Hao, X.-Q.; Hla, S.-W.;* Tu, Y.;* Li, X.* Synthesis of metallopolymers and direct visualization of the single polymer chain. J. Am. Chem. Soc., 2020, 142, 6196?6205.
3. Li, Z.; Wang, J.; Li, X.; Wang, Y.; Fan, L.-J.; Yang, S.; Guo, M.; Li, X.; Tu, Y.* Supramolecular and physically double-cross-linked network strategy toward strong and tough elastic fibers. ACS Macro Lett., 2020, 9, 1655?1661.
4. Li, Z.; Gu, J.; Qi, S.; Wu, D.; Gao, L.; Chen, Z.; Guo, J.; Li, X.; Wang, Y.; Yang, X.; Tu, Y.* Shackling effect induced property differences in metallo-supramolecular polymers. J. Am. Chem. Soc., 2017, 139, 14364?14367.
2023 第十三届高聚物分子与结构表征学术研讨会优秀研究生报告奖
2021 中国博士后科学基金
2021 深圳市海外高层次人才("孔雀计划")
2021 苏州大学优秀博士学位论文
2018 海峡两岸暨港澳高分子液晶态与超分子有序结构学术研讨会优秀墙报奖
2023 Outstanding Graduate Report Award of the 13th National Symposium on the Molecular and Structural Characterization of Polymers
2021 China Postdoctoral Science Foundation
2021 Peacock Talent, Shenzhen Municipal Government
2021 Excellent Doctoral Dissertation of Soochow University
2018 Excellent Poster Award of Cross Strait And Hong Kong Macao Academic Seminar On Polymer Liquid Crystal State and Supramolecular Ordered Structure